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    Title: Physical properties of phenanthrene-TCNQ complex
    Authors: Kao, H.-C. I.;Cheng, Ching Chih
    Contributors: 淡江大學化學學系
    Date: 1986-09
    Issue Date: 2013-07-09 15:28:08 (UTC+8)
    Publisher: Amsterdam: Elsevier BV * North-Holland
    Abstract: The 1:1 charge-transfer complex of phenanthrene (PH) and TCNQ has been prepared and characterized. It is stable at 195°C under nitrogen atmosphere. Its charge-transfer band is found at 520 nm (2.38 eV) in the solid state. Longitudinal electrical conductivity is 2.37 × 10−7 Scm−1 at 300 K with activation energy of 0.32 eV. The energy gap (0.64 eV) associated with this semiconductor is much smaller than the energy of the charge-transfer excitation. The diamagnetic susceptibility of this complex is found to be less than the sum of the constituent molecules indicates that PH-TCNQ is weakly paramagnetic.
    Relation: Physica B+C 143(1-3), pp.524-526
    DOI: 10.1016/0378-4363(86)90186-5
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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