New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25099

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题名:	New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties
作者:	魏和祥;Wei, Ho-hsiang;Lu, Jian-wei;Huang, Yao-hsuan;Lo, Shun-i
贡献者:	淡江大學化學學系
关键词:	Copper(II) complexes;Copper(II) clusters;Crystal structure;Magnetic properties
日期:	2007-10-01
上传时间:	2009-12-01
出版者:	Elsevier
摘要:	A new μ-oxo-bridged Cu(II) complex with cubane-like tetranuclear copper(II) complex, [Cu4(L1)4] · 4H2O (1) (H2L1 = 2-(3-methoxy-salicylidene-amino)-benzyl-alcohol), has been prepared, and structurally characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P21/n and has a tetranuclear core of Cu4O4. The temperature dependence of magnetic susceptibility measurements shown that complex 1 exhibits a strong antiferromagnetic interaction with J = −103.4 cm−1.
關聯:	Inorganic Chemistry Communications 10(10), pp.1210-1213
DOI:	10.1016/j.inoche.2007.07.009
显示于类别:	[化學學系暨研究所] 期刊論文

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