淡江大學機構典藏:Item 987654321/25099
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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25099


    Title: New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties
    Authors: 魏和祥;Wei, Ho-hsiang;Lu, Jian-wei;Huang, Yao-hsuan;Lo, Shun-i
    Contributors: 淡江大學化學學系
    Keywords: Copper(II) complexes;Copper(II) clusters;Crystal structure;Magnetic properties
    Date: 2007-10-01
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: A new μ-oxo-bridged Cu(II) complex with cubane-like tetranuclear copper(II) complex, [Cu4(L1)4] · 4H2O (1) (H2L1 = 2-(3-methoxy-salicylidene-amino)-benzyl-alcohol), has been prepared, and structurally characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P21/n and has a tetranuclear core of Cu4O4. The temperature dependence of magnetic susceptibility measurements shown that complex 1 exhibits a strong antiferromagnetic interaction with J = −103.4 cm−1.
    Relation: Inorganic Chemistry Communications 10(10), pp.1210-1213
    DOI: 10.1016/j.inoche.2007.07.009
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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