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    題名: New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand: Synthesis, crystal structure and magnetic properties
    作者: 魏和祥;Wei, Ho-hsiang;Lu, Jian-wei;Huang, Yao-hsuan;Lo, Shun-i
    貢獻者: 淡江大學化學學系
    關鍵詞: Copper(II) complexes;Copper(II) clusters;Crystal structure;Magnetic properties
    日期: 2007-10
    上傳時間: 2009-12-01
    出版者: Elsevier
    摘要: A new μ-oxo-bridged Cu(II) complex with cubane-like tetranuclear copper(II) complex, [Cu4(L1)4] · 4H2O (1) (H2L1 = 2-(3-methoxy-salicylidene-amino)-benzyl-alcohol), has been prepared, and structurally characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P21/n and has a tetranuclear core of Cu4O4. The temperature dependence of magnetic susceptibility measurements shown that complex 1 exhibits a strong antiferromagnetic interaction with J = −103.4 cm−1.
    關聯: Inorganic Chemistry Communications 10(10), pp.1210-1213
    DOI: 10.1016/j.inoche.2007.07.009
    顯示於類別:[化學學系暨研究所] 期刊論文

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