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    题名: New electron-capturing pentafluorophenyldialkylchlorosilanes as versatile derivatizing reagents for gas chromatography
    作者: 薛文發;Sye, Wen-fa;Poole, C. F.;Singhawangcha, S.;Hsu, F.;Zlatkis, A.;Arfwidsson, A.;Vessman, J.
    贡献者: 淡江大學化學學系
    日期: 1980-10-31
    上传时间: 2009-12-01
    出版者: Elsevier
    摘要: Flophemesyl, ISP-flophemesyl, tert.-buflophemesyl and CM-flophemesyl derivatives of a wide range of organic functional groups can be prepared and have good gas chromatographic and electron-capture detector properties. The derivatives are compared in terms of volatility, hydrolytic stability, detector response and mass spectral properties. Bis(pentafluorophenyl)chloromethylmethylsilane is evaluated as a reagent for preparing derivatives of strong nucleophiles. CM-flophemesyl chloride is evaluated as a cyclizing reagent for preparing derivatives of β- and γ-hydroxyamines. The flophemesyl derivative of N-nitrosodiethanolamine is shown to be suitable for detecting this compound at trace levels.
    關聯: Journal of Chromatography A 199, pp.123-142
    DOI: 10.1016/S0021-9673(01)91366-4
    显示于类别:[化學學系暨研究所] 期刊論文

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