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    題名: Mössbauer studies of photochemical reaction products of Ru(bpy)32+ iron cyanide double complexes
    作者: Wei, Ho-hsiang;Pan, W. B.
    貢獻者: 淡江大學化學學系
    日期: 1988-02
    上傳時間: 2009-12-01
    出版者: Dordrecht: Springer Netherlands
    摘要: The reductive and the oxidative electron-transfer photochemical reaction system of light-irradiated the mix solutions of Ru(bpy)3 2+ with [Fe(CN)6]4−, [Fe(CN)6]3−, [Fe(CN)5NO]2− and PB (Prussian Blue) have been studied. The double complexes which isolated from the precipitates of the photochemical reaction have been identified by means of Mössbauer spectroscopy. In order to clarify the chemical states of these isolated double complexes, we have (prepared and) studied Mössbauer spectra of the double complexes such as [Ru(bpy)3]3[Fe(CN)6]2.14H2O, [Ru(bpy)3]2[Fe(CN)6].10H2O, [Ru(bpy)3][Fe(CN)5NO].4H2O, and [Ru(bpy)3][PB]2.xH2O.
    關聯: Hyperfine interactions 40(1), pp.359-362
    DOI: 10.1007/BF02049117
    顯示於類別:[化學學系暨研究所] 期刊論文

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