A new aspect of size effect on the high-spin(5T2)-low-spin(1A1) transition in supported ferrous complexes

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/25079

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题名:	A new aspect of size effect on the high-spin(5T2)-low-spin(1A1) transition in supported ferrous complexes
作者:	Jean, Y. C.;Wei, Ho-hsiang
贡献者:	淡江大學化學學系
日期:	1986-02
上传时间:	2009-12-01
出版者:	Dordrecht: Springer Netherlands
摘要:	The temperature-dependent Mössbauer studies of carbon or MgO-supported Fe(ppi)2(NCS)2 show that the high-spin fraction fhs vs wt% Fe loading plots obtained at 298 K and 78 K have a crossover point (we say the critical size) near 5 wt% Fe size (l0μ size). For the SiO2-supported Fe(2-pic)3Cl2.EtOH (pic=2-picolylamine), the room temperature Mössbauer spectra show that the high-spin fraction decreases steeply with decreasing iron-complex loading.
關聯:	Hyperfine interactions 28(1), pp.705-709
DOI:	10.1007/BF02061544
显示于类别:	[化學學系暨研究所] 期刊論文

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