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    請使用永久網址來引用或連結此文件: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/25079

    題名: A new aspect of size effect on the high-spin(5T2)-low-spin(1A1) transition in supported ferrous complexes
    作者: Jean, Y. C.;Wei, Ho-hsiang
    貢獻者: 淡江大學化學學系
    日期: 1986-02
    上傳時間: 2009-12-01
    出版者: Dordrecht: Springer Netherlands
    摘要: The temperature-dependent Mössbauer studies of carbon or MgO-supported Fe(ppi)2(NCS)2 show that the high-spin fraction fhs vs wt% Fe loading plots obtained at 298 K and 78 K have a crossover point (we say the critical size) near 5 wt% Fe size (l0μ size). For the SiO2-supported Fe(2-pic)3Cl2.EtOH (pic=2-picolylamine), the room temperature Mössbauer spectra show that the high-spin fraction decreases steeply with decreasing iron-complex loading.
    關聯: Hyperfine interactions 28(1), pp.705-709
    DOI: 10.1007/BF02061544
    顯示於類別:[化學學系暨研究所] 期刊論文


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