English  |  正體中文  |  简体中文  |  Items with full text/Total items : 51510/86705 (59%)
Visitors : 8276094      Online Users : 102
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25079

    Title: A new aspect of size effect on the high-spin(5T2)-low-spin(1A1) transition in supported ferrous complexes
    Authors: Jean, Y. C.;Wei, Ho-hsiang
    Contributors: 淡江大學化學學系
    Date: 1986-02
    Issue Date: 2009-12-01
    Publisher: Dordrecht: Springer Netherlands
    Abstract: The temperature-dependent Mössbauer studies of carbon or MgO-supported Fe(ppi)2(NCS)2 show that the high-spin fraction fhs vs wt% Fe loading plots obtained at 298 K and 78 K have a crossover point (we say the critical size) near 5 wt% Fe size (l0μ size). For the SiO2-supported Fe(2-pic)3Cl2.EtOH (pic=2-picolylamine), the room temperature Mössbauer spectra show that the high-spin fraction decreases steeply with decreasing iron-complex loading.
    Relation: Hyperfine interactions 28(1), pp.705-709
    DOI: 10.1007/BF02061544
    Appears in Collections:[化學學系暨研究所] 期刊論文

    Files in This Item:

    There are no files associated with this item.

    All items in 機構典藏 are protected by copyright, with all rights reserved.

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback