English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 49350/84015 (59%)
造訪人次 : 7266631      線上人數 : 42
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25063

    題名: Mössbauer and magnetic studies on the spin states of diiron(III)-porphyrin dicopper(II) complexes
    作者: Huang, S. F.;Wei, Ho-hsiang
    貢獻者: 淡江大學化學學系
    日期: 1994-12
    上傳時間: 2009-12-01
    出版者: Dordrecht: Springer Netherlands
    摘要: Several biological model complexes of cytochrome c oxidase analogues, such as X2(TPP)2Fe2(Apen)Cu2Cl4, where TPP=5, 10, 15, 20-tetraphenylporphine, Apen=bis(acetylpyrazine)-ethylenediimine, X=Cl−, N 3 −, Im, 1-Me-Im, 2-Me-Im, 4-Me-Im and OCH 3 −, were prepared. The electronic spin states of these complexes in solid state were studied by means of Mössbauer and EPR spectroscopies and magnetic susceptibility measurements. The iron(III) atom of these complexes is present in different spin states, depending upon the nature of the axial ligand X of Fe(III)-porphyrin; the N 3 −, Cl−, OCH 3 −, 2-Me-Im axial groups lead to complexes in a pure high-spin state independent of temperature. In contrast, the imidazole axial groups (e.g. Im, 4-Me-Im) behave differently and all show a temperature dependence of the6A1 ↔2T2 spin transition. The magnetic exchange behavior between Fe and Cu atoms in the present complexes is also discussed.
    關聯: Hyperfine interactions 91(1), pp.809-814
    DOI: 10.1007/BF02064611
    顯示於類別:[化學學系暨研究所] 期刊論文





    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋