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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25030


    Title: Lewis Acid-Promoted Reduction of Bis (Triorganotin) Oxides to Hexaorganoditins
    Authors: 李世元;Lee, Adam Shih-yuan;曾喜樑;Zhang, Shi-lien;潘安國;Pan, Ohm-guo
    Contributors: 淡江大學化學學系
    Keywords: Hexaorganoditin;Triorganotin Oxide;Lewis Acid;Reduction;六有機二錫;三有機錫氧化物;路易士酸;還原
    Date: 1997-12
    Issue Date: 2013-07-29 13:47:50 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: Hexalkylditin is prepared by a Lewis acid-promoted(MgCl/sub 2/) reductive reaction of bis(trialkyltin) oxide using magnesium metal as reducing agent. Hexabutyl- and hexaphenylditin are synthesized with 95% and 80% yield separately and a radical mechanism is proposed for the reaction condition. Unsymmetric ditin, Bu/sub 3/Sn- SnPh/sub 3/, was first synthesized by this reductive method.
    Relation: Journal of the Chinese Chemical Society=中國化學會會誌 44(6), pp.625-628
    DOI: 10.1002/jccs.199700096
    Appears in Collections:[化學學系暨研究所] 期刊論文

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