English  |  正體中文  |  简体中文  |  Items with full text/Total items : 49287/83828 (59%)
Visitors : 7156038      Online Users : 64
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/25016


    Title: Intraligand substituent effect on high-spin(5T2) low-spin(1A1)transition in solid(dithiocyanato)bis(N-R-2-pyridinaldimine)iron(II)
    Authors: 魏和祥;Wei, Ho-hsiang;高世平;Kao, S. P.
    Contributors: 淡江大學化學學系
    Keywords: Mossbauer effect;iron-complexes
    Date: 1985-12
    Issue Date: 2013-06-07 10:32:37 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: The spin transition of high-spin (/sup 5/T/sub 2/).harlor.low-spin (/sup 1/A/sub 1/) of (dithiocyanato) (N-phenyl-2-pyridinaldimine) iron (II) complexes can be altered by substituents on the phenyl ring. Mossbauer spectra at 78 K for the 4-substituted derivatives (with the exception of the 4-OH-substituted derivative) indicate that the fraction of low-spin states increases with decreasing substituent electron-withdrawing ability, as measured by the Hammet .sigma. constant (4-OCH/sub 3/<4-CH/sub 3/CONH 4-C/sub 6/H/sub 5/<4-CH/sub 3/<4-H<4-Cl<4-NO/sub 2/). In addition, the effect of methyl-substitution at the ortho-, meta- or paraposition of the phenyl ring on the apin transition was examined. Mossbauer spectra of these methyl-substituted complexes reveal quite different spin equilibria.
    The spin transition of high-spin (/sup 5/T/sub 2/).harlor.low-spin (/sup 1/A/sub 1/) of (dithiocyanato) (N-phenyl-2-pyridinaldimine) iron (II) complexes can be altered by substituents on the phenyl ring. Mossbauer spectra at 78 K for the 4-substituted derivatives (with the exception of the 4-OH-substituted derivative) indicate that the fraction of low-spin states increases with decreasing substituent electron-withdrawing ability, as measured by the Hammet .sigma. constant (4-OCH/sub 3/<4-CH/sub 3/CONH 4-C/sub 6/H/sub 5/<4-CH/sub 3/<4-H<4-Cl<4-NO/sub 2/). In addition, the effect of methyl-substitution at the ortho-, meta- or paraposition of the phenyl ring on the apin transition was examined. Mossbauer spectra of these methyl-substituted complexes reveal quite different spin equilibria.
    Relation: 中國化學會會誌=Journal of the Chinese Chemical Society 32(4),頁399-403
    DOI: 
    Appears in Collections:[化學學系暨研究所] 期刊論文

    Files in This Item:

    File SizeFormat
    0009-4536_32(4)p399-403.pdf198KbAdobe PDF101View/Open

    All items in 機構典藏 are protected by copyright, with all rights reserved.


    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback