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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24982

    Title: Ferromagnetic Exchange in Two Dicopper(II) Complexes Using a μ-Alkoxo-μ-7-azaindolate Bridge
    Authors: Chou, Yi-chian;Huang, Shu-fei;Koner, Rajesh;Lee, Gene-hsiang;Wang, Yu;Mohanta, Sasankasekhar;魏和祥;Wei, Ho-hsiang
    Contributors: 淡江大學化學學系
    Date: 2004-05-03
    Issue Date: 2009-12-01
    Publisher: American Chemical Society (ACS)
    Abstract: Syntheses, structures, and magnetic properties of two heterobridged μ-alkoxo-μ-7-azaindolate dicopper(II) complexes, [CuII2(L−F)(μ-C7H5N2)] (1) and [CuII2(L−H)(μ-C7H5N2)]·CH3OH (2) (H3L−F = 1,3-bis(3-fluorosalicylideneamino)-2-propanol; H3L−H = 1,3-bis(salicylideneamino)-2-propanol) have been reported. Aside from being a new type of heterobridged complex, 1 and 2 exhibit ferromagnetic interaction (2J = 52 cm-1 for 1 and 33.4 cm-1 for 2) despite orbital complementarity (7-azaindolate HOMO is antisymmetric).
    Relation: Inorganic chemistry 43(9), pp.2759-2761
    DOI: 10.1021/ic035322t
    Appears in Collections:[化學學系暨研究所] 期刊論文

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