Ferro-and Antiferromagnetic Properties of Metal Complexes with Pyridine-substituted Nitronyl Nitroxide Radicals

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/24977

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题名:	Ferro-and Antiferromagnetic Properties of Metal Complexes with Pyridine-substituted Nitronyl Nitroxide Radicals
作者:	魏和祥;Wei, Ho-hsiang;翁宏岳;Wong, H. Y.;李錦祥;Lee, G. H.;王瑜;Wang, yu
贡献者:	淡江大學化學學系
关键词:	Molecular Magnetic Property;Metal Complex;Free Radical;Ferromagnetism;Antiferromagnetic Property;Nitronyl Nitroxise;分子磁性質;金屬錯合物;自由基;鐵磁性;反鐵磁性質
日期:	1996-06-01
上传时间:	2013-07-29 13:45:26 (UTC+8)
出版者:	臺北市：中國化學學會
摘要:	The synthesis, crystal structure and magnetic properties of the non-transition metals; Cd(II), Zn(II), Hg(II), Mg(II) and the transition metals; Co(II), Ni(II), Cu(II) complexes with 2-(4-pyridyl)-4,4,5,5- tetramethylimidazolinyl-1-oxy-3-oxide ( NITpPy) are presented. The compounds of free radical NITpPy, HgCl/sub 2/ (NITpPy), and Zn(acac)/sub 2/(NITpPy) crystallize in the same monoclinic system of space group C2/c. The magnetic properties of the temperature-dependent magnetic susceptibility of NITpPy and its metal complexes are discussed according to the Heisenberg model. A weak ferromagnetic coupling in NITpPy and a weak antiferromagnetic coupling in the metal complexes have been revealed.
關聯:	Journal of the Chinese Chemical Society=中國化學會會誌 43(3), pp.253-259
DOI:	10.1002/jccs.199600038
显示于类别:	[化學學系暨研究所] 期刊論文

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