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    題名: Ferro-and Antiferromagnetic Properties of Metal Complexes with Pyridine-substituted Nitronyl Nitroxide Radicals
    作者: 魏和祥;Wei, Ho-hsiang;翁宏岳;Wong, H. Y.;李錦祥;Lee, G. H.;王瑜;Wang, yu
    貢獻者: 淡江大學化學學系
    關鍵詞: Molecular Magnetic Property;Metal Complex;Free Radical;Ferromagnetism;Antiferromagnetic Property;Nitronyl Nitroxise;分子磁性質;金屬錯合物;自由基;鐵磁性;反鐵磁性質
    日期: 1996-06-01
    上傳時間: 2013-07-29 13:45:26 (UTC+8)
    出版者: 臺北市:中國化學學會
    摘要: The synthesis, crystal structure and magnetic properties of the non-transition metals; Cd(II), Zn(II), Hg(II), Mg(II) and the transition metals; Co(II), Ni(II), Cu(II) complexes with 2-(4-pyridyl)-4,4,5,5- tetramethylimidazolinyl-1-oxy-3-oxide ( NITpPy) are presented. The compounds of free radical NITpPy, HgCl/sub 2/ (NITpPy), and Zn(acac)/sub 2/(NITpPy) crystallize in the same monoclinic system of space group C2/c. The magnetic properties of the temperature-dependent magnetic susceptibility of NITpPy and its metal complexes are discussed according to the Heisenberg model. A weak ferromagnetic coupling in NITpPy and a weak antiferromagnetic coupling in the metal complexes have been revealed.
    關聯: Journal of the Chinese Chemical Society=中國化學會會誌 43(3), pp.253-259
    DOI: 10.1002/jccs.199600038
    顯示於類別:[化學學系暨研究所] 期刊論文

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