Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid

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Title:	Epoxidation of protected (1,4,5)-cyclohex-2-ene-triols and their acid hydrolysis to synthesize quercitols from D-(-)-quinic acid
Authors:	Shih, T. L.;Lin, Y. L.
Contributors:	淡江大學化學學系
Keywords:	1,4,5 cyclohex 2 ene triol derivative;butane 2,3 bisacetal;cyclohexene derivative;cyclohexylidene acetal;epoxide;quercitol;quinic acid;unclassified drug;article;chemical reaction kinetics;epoxidation;hydrolysis;stereochemistry;synthesis
Date:	2005-07
Issue Date:	2013-08-08 14:43:51 (UTC+8)
Publisher:	Philadelphia: Taylor & Francis Inc.
Abstract:	Highly stereoselective epoxidations have been achieved in both cyclohexylidene acetal and butane 2,3‐bisacetal (BBA) protection of (1,4,5)‐cyclohex‐2‐ene‐triols. These epoxy derivatives are all derived from D‐(−)‐quinic acid and can be used for the synthesis of muco‐, (+)‐epi‐, (+)‐vibo, (−)‐talo, and (−)‐gala‐quercitols.
Relation:	Synthetic Communications 35(13), pp.1809-1817
DOI:	10.1081/SCC-200063960
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

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