By controlling the current density, pH and temperature of the electrodepositing iron-zinc bath, various compositions of electrodeposited Fe/sub 1-x/Zn/sub x/ (0.95 > x > 0.15) alloys on Al-foil have been prepared. The electronic state, intermetallic phases and magnetic hyperfine interactions have been studied by means of /sup 57/Fe Mossbauer spectroscopy at 298K for these electrodeposited Fe-Zn alloys. The isomer shifts obtained from the Mossbauer spectral of the alloys increased with increasing Zn content. An alloy containing above 50% Fe, exhibits a linear dependence of the internal magnetic field, Hin, on the Zn content.
Relation:
Journal of the Chinese Chemical Society=中國化學會會誌 35(4), pp.267-271
