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    題名: Electrochemical dopping of tetramethylammonium ions into C60 film
    作者: 王文竹;Wang, Wen-jwu;Chiu, H. S.;Lin, S. S.;Chang, C. S.;Chuang, K. S.
    貢獻者: 淡江大學化學學系
    日期: 1998
    上傳時間: 2009-12-01
    出版者: Marcel Dekker
    摘要: The electrochemical properties of C60 films were studied by cyclic voltammetry and electrochemical quartz crystal microbalance technique in organic electrolyte solution. Tetramethylammonium perchlorate was used as a supporting electrolyte in acetonitrile solution. Thin films are prepared by solvent quickly evaporated method on a preheated glassy carbon electrode. The electrochemical response of C60 films is consistent with a reduction mechanism that is dominated by ion transport to form contact ion pair. In the proposed mechanism, swelling of the film with solvent and intercalation of cations into the film proceed parallelly. The stability of the film with respect to successive redox cycles was also interpreted.
    關聯: Fullerene science and technology 6, pp.681-688
    DOI: 10.1080/10641229809350228
    顯示於類別:[化學學系暨研究所] 期刊論文

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