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    題名: Electrochemiacl doping of tetraethylammonium on C60 film
    其他題名: 以電化學方法植入Tetraethylammonium在C60薄膜中
    作者: 王文竹;Wang, Wen-jwu;Chiu, Hau-shy;余良杰;Yu, Liang-jye;王伯昌;Wang, Bo-cheng
    貢獻者: 淡江大學化學學系
    日期: 1995-03-15
    上傳時間: 2009-12-01
    出版者: Elsevier
    摘要: The electrochemical behavior of C60 films, which was prepared on electrode by solution casting method, during redox processes in acetonitrile solution containing tetraethylammonium perchlorate as supporting electrolyte was examined by means of cyclic voltammetry (CV) and electrochemical quartz crystal microbalance (EQCM) technique. In the CV behavior, there are four reductive waves at R1=-1.17 V, R2=-1.25 V, R3=-1.40 V and R4=-1.55 V vsFc/Fc+ which are corresponding to C60(TEA+)/C60-(TEA+), C60/C60, C60 (TEA+)/C60−2 reactions, respectively. There are four reoxidative waves at 04=-1.29 V, 03=-1.06 V, 02=-0.76 V and 01=-0.55 V vs Fc/Fc+ which are corresponding to C60−2 deposition on film, C60-/C60, and C60−2(TEA+)2/C60-(TEA+)/C60(TEA-), respectively. The dissolution/ depositive of C60−n(n=1,2) and doping / dedoping of TEA+ on C60 films at different potential are investigated and approved by EQCM studied.
    關聯: Synthetic metals 70(1-3), pp.1439-1442
    DOI: 10.1016/0379-6779(94)02909-I
    顯示於類別:[化學學系暨研究所] 期刊論文

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