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    Title: Crystal Structure and Magnetic Properties of Pyridyl-Substituted Nitronyl Nitroxides
    Authors: 李綺縑;魏和祥;李錦祥;王瑜
    Contributors: 淡江大學化學學系
    Keywords: Molecular magnetism;Crystal structure;Organic radicals;Nitronyl nitroxides
    Date: 1998-06
    Issue Date: 2013-07-29 13:42:47 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: X-ray crystal structure and cryomagnetic properties of three organic radicals, 2-(2-pyridyl)-4,4,5,5-tetramehyl-4,5-dihydro-1-H-imidazol-1-oxyl-3-N-oxide(NIT-oPy) 1,2-(3-pyridyl)4,4,5,5,-tetramethyl-4,5-dihydro-1-H-imidazol-1-oxyl-3-N-oxide(NIT-mPy) 2 and 2-(6-methyl-2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1-H-imidazol-1-oxyl-3-N-oxide(NIT-6M-oPy) 3 were investigated. The crystal structures of compounds 1-3 show the same feature of a P2 1/c space group of a monoclinic system. Two crystal-lographically independent molecules were found in the crystals of compounds 1-3. The temperature dependence of magnetic susceptibility of compounds 1-3 revealed an intermolecular antiferromagnetic exchange interaction.
    Relation: Journal of the Chinese Chemical Society=中國化學會會誌 45(3), pp.349-353
    DOI: 10.1002/jccs.199800055
    Appears in Collections:[化學學系暨研究所] 期刊論文

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