淡江大學機構典藏:Item 987654321/24898
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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/24898


    Title: Correlation Between Polarographic Half-Wave Potentials and Electronic Spectra of Cis-Trans Complexes of Chromium (Ⅲ) and Rhodium (Ⅲ)
    Authors: Wei, Ho-hsiang
    Contributors: 淡江大學化學學系
    Date: 1977-12
    Issue Date: 2013-07-29 13:40:52 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: A linear correlation between half-wave potential (E1/2) for the process M(III)→M(II) and the first d-d transition band (v) of the types cis and trans-[M(en)2X2]n+ (M=Cr(III), and Rh(III), X=ONO¯, NCS¯, F¯, Cl¯, Br¯, I¯, H2O, DMF, DMSO, n=1, 3) was found. The plots of the difference in half-wave potential (⊿E1/2) against the difference in the first d-d transition band (⊿v) for the cis and trans isomer are straight lines. The equations, E1/2=β/nαF+K1 and ⊿E1/2=(β/NαF)⊿ε were derived, and used to describe the linear correlations between polarographic behavior and electronic spectrum.
    Relation: Journal of the Chinese Chemical Society 24(4),頁147-156
    DOI: 10.1002/jccs.197700025
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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