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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24898

    Title: Correlation Between Polarographic Half-Wave Potentials and Electronic Spectra of Cis-Trans Complexes of Chromium (Ⅲ) and Rhodium (Ⅲ)
    Authors: 魏和祥;Wei, Ho-hsiang;Li, Ting-tung
    Contributors: 淡江大學化學學系
    Date: 1977-12
    Issue Date: 2013-07-29 13:40:52 (UTC+8)
    Publisher: 臺北市:中國化學學會
    Abstract: A linear correlation between half-wave potential (E1/2) for the process M(III)→M(II) and the first d-d transition band (v) of the types cis and trans-[M(en)2X2]n+ (M=Cr(III), and Rh(III), X=ONO¯, NCS¯, F¯, Cl¯, Br¯, I¯, H2O, DMF, DMSO, n=1, 3) was found. The plots of the difference in half-wave potential (⊿E1/2) against the difference in the first d-d transition band (⊿v) for the cis and trans isomer are straight lines. The equations, E1/2=β/nαF+K1 and ⊿E1/2=(β/NαF)⊿ε were derived, and used to describe the linear correlations between polarographic behavior and electronic spectrum.
    Relation: 中國化學會會誌=Journal of the Chinese Chemical Society 24(4),頁147-156
    Appears in Collections:[化學學系暨研究所] 期刊論文

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