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    Title: Comparison of properties of conducting TCNQ salts with 1,4-bis[1-(4--r-pyridinio)]butane and trans-2-butene dications
    Authors: 余良杰;Yu, L. J.
    Contributors: 淡江大學化學學系
    Date: 1991-05-15
    Issue Date: 2009-12-01
    Publisher: Elsevier
    Abstract: Conducting TCNQ salts are prepared with dications consisting of butyl and trans-2-butenyl as the central linkages and various 4-substituted pyridinium as the charged end groups. Conductivities are comparable and of low values (10−4 − 10−2 S/cm) for the salts having H, t-butyl and benzyl as the substituents of pyridine irrespective of central linkages. For the salts with 4-methyl and 4-ethyl as the substituents of pyridine, the conductivities are 4 orders of magnitude higher for butyl linkage. UV-VIS-Near IR and IR spectra of these salts are presented. The variation of conductivity is explained in terms of dication structures.
    Relation: Synthetic metals 42(1-2), pp.1751-1756
    DOI: 10.1016/0379-6779(91)91945-7
    Appears in Collections:[化學學系暨研究所] 期刊論文

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