淡江大學機構典藏:Item 987654321/24880
English  |  正體中文  |  简体中文  |  Items with full text/Total items : 62830/95882 (66%)
Visitors : 4047822      Online Users : 588
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
    •  Adv. Search
    Home ‧ Login ‧ Upload ‧ Help ‧ About ‧ Administer Goto mobile version


    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/24880


    Title: Comparing differentiation of xylene isomers by electronic ionization, chemical ionization and self-ion/molecule reactions and the first observation of methyne addition ions for xylene isomers in self-ion/molecule reactions for non-nitrogenated compounds
    Authors: 吳慧芬;Wu, Hui-fen;Wu, Wen-feng
    Contributors: 淡江大學化學學系
    Date: 2003-10-15
    Issue Date: 2009-12-01
    Publisher: John Wiley & Sons
    Abstract: This study presents the self-ion/molecule reaction (SIMR) spectra of three xylene isomers, and proposes an approach to differentiating them based on observed differences in relative abundances of ions formed by SIMR in an internal source ion trap instrument. It also demonstrates the applicability of SIMR for isomer discrimination, which is better than electron ionization (EI) and dimethyl ether chemical ionization (DME CI) in an ion trap mass spectrometer (ITMS) since no CI reagent, metal ions or internal standards are required to perform SIMR. The merits of the new method for distinguishing isomers are that it is simple, rapid and economic. To date, methyne addition products ([M+13]+ ions) have been observed for several nitrogenated compounds including aza-crown ethers, aniline and dopamine from SIMR in the ITMS. The xylene isomers are, however, the first three non-nitrogenated compounds that have been shown to produce the methyne addition ions in SIMR.
    Relation: Rapid Communications in Mass Spectrometry 17(21), pp.2399-2406
    DOI: 10.1002/rcm.1203
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

    Files in This Item:

    File Description SizeFormat
    0KbUnknown267View/Open
    rcm.1203.pdf164KbAdobe PDF2View/Open

    All items in 機構典藏 are protected by copyright, with all rights reserved.

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback