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http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/24864
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| Title: | Charge-transfer salt of bis(cis-1,2-diphenylethene-1,2-dithiolato)palladate(1 –) with cobaltocenium, and neutral bis(cis-1,2-diphenylethene-1,2-dithiolato)palladium |
| Authors: | Sheu, Chou-fu;李榮熹;Lee, Jung-si |
| Contributors: | 淡江大學化學學系 |
| Date: | 1999-07 |
| Issue Date: | 2009-12-01 |
| Publisher: | Malden: Wiley-Blackwell Publishing, Inc. |
| Abstract: | The crystal structure of the charge-transfer salt cobalto-cenium bis(cis-1,2-diphenylethene-1,2-dithiolatato)palladate(1-), [CO(C5H5)(2)][Pd{S2C2(C6H5)(2)}(2)], consists of linear -D(+)A(-)D(+)A(-)D(+)A(-)- chains. The [Co(C5H5)(2)](+) cation adopts an approximately eclipsed D-5h configuration. The stereochemistry of the [Pd{S2C2(C6H5)(2)}(2)](-) anion is largely similar to that of the neutral molecule, bis(cis-1,2-diphenylethene-1,2-dithiolato)palladium, [Pd-{S2C2(C6H5)(2)}(2)], the structure of which has also been determined; however, the Pd atom of the former has a distorted square-planar environment, while the PdS4 chromophore of the latter is strictly planar. Furthermore, the former has longer Pd-S and S-C distances, and shorter C-C distances (in the chelate rings) than the latter. |
| Relation: | Acta Crystallographica, Section C 55(7), pp.1069-1072 |
| DOI: | 10.1107/S0108270199004564 |
| Appears in Collections: | [化學學系暨研究所] 期刊論文
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