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    題名: Self-curable system of an aqueous-based polyurethane dispersion via a ring-opening reaction of azetidine end groups
    作者: Wang, Shih-Chieh;Chen, Pao-cheng;Yeh, Jet-tao;Chen, Kan-nan
    貢獻者: 淡江大學化學學系
    關鍵詞: crosslinking;dispersions;functionalization of polymers;polyurethanes
    日期: 2006-12-05
    上傳時間: 2009-11-04 16:55:49 (UTC+8)
    出版者: John Wiley & Sons
    摘要: An azetidine (AZT) containing compound, 3-azetidinyl propanol was synthesized from methyl acrylate with 3-amino-1-propanol in a four-step reaction. It was introduced into an isocyanate-terminated carboxylic acid containing polyurethane (PU) prepolymer as the end group. A single-component, AZT-terminated self-curable aqueous-based PU dispersion was obtained from the water dispersion process after it was neutralized with triethylamine. Its carboxylic groups served not only as the internal emulsifier stabilizing the aqueous PU dispersion but also as PU self-curing sites toward its AZT end groups via a ring-opening reaction. The curing reaction took place on drying and resulted in polymeric network structure formation among the polymers. The performance properties of this self-cured PU were evaluated in this study.
    關聯: Journal of Applied Polymer Science 102(5), pp.4383-4393
    DOI: 10.1002/app.25013
    顯示於類別:[化學學系暨研究所] 期刊論文


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