Independent syntheses of the products of acid- and base-catalyzed rearrangements of 2-(1-isoquinolyl)-3,3,5-triarylpyrrolenines

機構典藏 > College of Sciences > Graduate Institute & Department of Chemistry > Journal Article > Item 987654321/19516

Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/19516

Title:	Independent syntheses of the products of acid- and base-catalyzed rearrangements of 2-(1-isoquinolyl)-3,3,5-triarylpyrrolenines
Authors:	McEwen, William E.;Berkeile, David H.;Liao, Tsung-kai;林雲山;Lin, Yun-shan
Contributors:	淡江大學化學學系
Date:	1971-01
Issue Date:	2009-11-04 16:51:55 (UTC+8)
Publisher:	Washington: American Chemical Society (ACS)
Abstract:	2-( l-Isoquinoly1)-3,4,5- triphenylpyrrole (4) and 2-( l-isoquinolyl)-3-p-anisyl-4,5-diphenylpyrrole (6) have been synthesized by unambiguous methods. The synthetic samples are identical with the products of the acid- or base-catalyzed isomerization of 2-( l-isoquinolyl)-3,3,5-triphenylpyrrolenine (3) and the base-catalyzed isomerization of 2-( l-isoquinolyl)-3-p-anisyl-3,5-diphenylpyrro1eni(n2e l ), respectively. By inference, 2-( 1-isoquinoly1)- 4-p-ani~yl-3~5-diphenylpyrro(l7e) is the product of the acid-catalyzed isomerization of 2 1. These facts provide additional support for the mechanisms of the isomerization reactions proposed in previous papers.
Relation:	Journal of Organic Chemistry 36(11), pp.1459-1462
DOI:	10.1021/jo00810a003
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

Files in This Item:

File	Description	Size	Format
0022-3263_36(11)p1459-1462.pdf		625Kb	Adobe PDF	378	View/Open
Independent syntheses of the products of acid- and base-catalyzed rearrangements of 2-(1-isoquinolyl)-3,3,5-triarylpyrrolenines.pdf		621Kb	Adobe PDF	2	View/Open