淡江大學機構典藏:Item 987654321/125746
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    题名: Nitrogen substitution induced lattice contraction in nickel nanoparticles for electrochemical hydrogen evolution from simulated seawater
    作者: B. Singh, A. K. Singh, A. Priyadarsini, Y. C. Huang, S. Dey, T. Ansari, S. Shen, G. K. Lahirin, C. L. Dong, B. S. Mallik and A. Indra
    日期: 2023-04-21
    上传时间: 2024-07-31 12:11:36 (UTC+8)
    出版者: Royal Society of Chemistry
    摘要: Herein, we demonstrate a facile method for the introduction of nitrogen in the lattices of nickel nanoparticles to form NiNx (x = 0.13, 0.20, 0.27). X-ray absorption spectroscopy reveals the contraction of the Ni–Ni bond and modulated coordination environment after nitrogen introduction. The NiN0.20 required 87 mV overpotential for −10 mA cm−2 cathodic current density in simulated seawater. The density functional theory calculations revealed favorable EH2Oads and ΔGHads after N-introduction.
    關聯: Chemical Communications 59(40), p.6084-6087
    DOI: 10.1039/D3CC01801F
    显示于类别:[電機工程學系暨研究所] 期刊論文

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