淡江大學機構典藏:Item 987654321/125735
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    题名: Cooperation of oxygen vacancy and FeIII/FeII sites in H2-reduced Fe-MIL-101 for enhanced Fenton-like degradation of organic pollutants
    作者: Bao, Chaosheng;Wang, Hu;Wang, Caiyun;Zhang, Xiaohui;Zhao, Xiaoliang;Dong, Chung-Li;Huang, Yu-Cheng;Chen, Shuai;Guo, Peng;She, Xilin;Sun, Yuanyuan;Yang, Dongjiang
    关键词: Fe-MIL-101;Mixed valence;Oxygen vacancy;Heterogeneous Fenton-like reaction;Degradation
    日期: 2023-01-05
    上传时间: 2024-07-31 12:11:03 (UTC+8)
    出版者: Elsevier
    摘要: Metal-organic frameworks (MOFs)-based Fenton-like catalysts with mixed-valence and oxygen vacancies (OVs) were designed by H2 reduction of Fe-MIL-101 to activate H2O2. The degradation efficiency of norfloxacin (NOR) by Fe-MIL-101 treated at 220 °C (Fe-MIL-101-H-220) (100 %) was significantly higher than that of original Fe-MIL-101 (51.1 %) and showed excellent degradation efficiency for other pollutants. Moreover, the Fe-MIL-101-H-220/H2O2 system exhibited superior degradation efficiency for NOR over a wide pH range and could maintain 93.6 % after 5 cycles. The high performance is assigned to the cooperation of OVs and FeIII/FeII sites·H2O2 could be rapidly activated to produce •OH at the FeII sites. Further, electron-rich OVs sites could increase the interaction between adjacent FeIII sites and H2O2, benefitting the reduction of FeIII site to FeII site and accelerating FeIII/FeII cycle. This study provides a new strategy for the enhanced Fenton-like degradation of pollutants using iron-based MOFs catalyst, and unveils the intrinsic origin of the superior activity of thermally reduced Fe-MIL-101 for H2O2 activation.
    關聯: Journal of Hazardous Materials 441, 129922
    DOI: 10.1016/j.jhazmat.2022.129922
    显示于类别:[電機工程學系暨研究所] 期刊論文

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