淡江大學機構典藏:Item 987654321/124323
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    题名: Robust Synthesis of Tetra-Boronate Esters Analogues and the Corresponding Boronic Acids Derivatives
    作者: Pan, Po-shen
    关键词: Boronic acid;Deprotection;Microwave chemistry;Multicomponent reactions;Ugi-4CR
    日期: 2022-05-02
    上传时间: 2023-08-02 12:05:11 (UTC+8)
    摘要: Organoboron compounds are widely used in catalytic reactions, medicinal chemistry, chemosensors, and polymer applications, because of their low toxicity, high stability, Lewis acidity, chemical versatility, and ability to form covalent bonds with their nucleophilic targets, In this report, we demonstrate how to efficiently assemble tetra boronate-containing compounds at the gram-scale via a one-pot modified microwave-assisted Ugi-4CR reaction. These boronate esters can then be transformed into the corresponding boronic acids under a reliable deprotection method, also reported herein.
    關聯: European Journal of Organic Chemistry 2022(31),　e202200379
    DOI: 10.1002/ejoc.202200379
    显示于类别:[化學學系暨研究所] 期刊論文

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