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    題名: A comparative study of electrochemical cells for in situ x-ray spectroscopies in the soft and tender x-ray range
    作者: Juan-Jesús Velasco-Vélez;Falling, Lorenz J;Bernsmeier, Denis;Sear, Michael J;Clark, Pip C J;Chan, Ting-Shan;Eugen Stotz, Michael Hävecker;Ralph Kraehnert;Axel, Knop-Gericke;Chuang, Cheng-Hao;Starr, David E;Favaro, Marco;Mom, Rik V
    關鍵詞: in situ x-ray spectroscopy;electrochemistry;x-ray absorption spectroscopy;x-ray photoelectron spectroscopy;spectroelectrochemistry
    日期: 2021-01-20
    上傳時間: 2021-08-18 12:11:06 (UTC+8)
    摘要: In situ x-ray spectroscopies offer a powerful way to understand the electronic structure of the electrode–electrolyte interface under operating conditions. However, most x-ray techniques require vacuum, making it necessary to design spectro-electrochemical cells with a delicate interface to the wet electrochemical environment. The design of the cell often dictates what measurements can be done and which electrochemical processes can be studied. Hence, it is important to pick the right spectro-electrochemical cell for the process of interest. To facilitate this choice, and to highlight the challenges in cell design, we critically review four recent, successful cell designs. Using several case studies, we investigate the opportunities and limitations that arise in practical experiments.
    關聯: J. Phys. D: Appl. Phys. 54, 124003
    DOI: 10.1088/1361-6463/abd2ed
    顯示於類別:[電機工程學系暨研究所] 期刊論文

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