Two new pyrophosphates nonlinear optical (NLO) materials, Rb3PbBi(P2O7)2 (I) and Cs3PbBi(P2O7)2 (II), were successfully designed and synthesized. Both compounds exhibit large NLO effects and birefringences. Material I presents the scarce case of possessing the coexistence of large birefringence (0.031 at 1064 nm and 0.037 at 532 nm) and second harmonic generation (SHG) response (2.8× potassium dihydrogen phosphate (KDP)) in ultraviolet NLO phosphates and its SHG is the largest in the phase‐matching (PM) pyrophosphates. Both I and II have three‐dimensional (3D) crystal structures composed of corner‐shared RbO12 (CsO11), RbO10 (CsO10), BiO6, PbO7 (PbO6) and P2O7 groups, in which P2O7 and PbO7 (PbO6) units form an alveolate [PbPO]∞ skeleton frame. Theoretical calculations reveal that the P−O, Bi−O and Pb−O units are mainly responsible for the moderate birefringence and large SHG efficiency of I.
關聯:
Angewandte Chemie International Edition 59(40), p.17648 -17656
