Catalyst-free synthesis of borodepsipeptides using isocyano arylboronate under aqueous condition

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Title:	Catalyst-free synthesis of borodepsipeptides using isocyano arylboronate under aqueous condition
Authors:	Chiang, Yao-Yu;Kuo, Yi-Chen;Lin, Sung-Chi;Yeh, Pei-Yin;Chen, Yi-Wei;Pan, Po-Shen
Keywords:	No catalyst;Room temperature;Passerini;Isocyano-boronate esters;Multicomponent reaction
Date:	2020-08-25
Issue Date:	2021-05-06 12:11:10 (UTC+8)
Publisher:	Springer
Abstract:	Herein, the synthesis of borodepsipeptides utilizing boron-containing isocyanides is described. The target compounds were synthesized via Passerini three-component reaction (P-3CR), in which H2O was utilized as the solvent. Further, unlike conventional P-3CR, where Lewis acid catalysts are often required, the reported method requires no catalyst and proceeds in room temperature. A variety of aldehydes and acids were used as the building blocks to generate the desired products.
Relation:	Research on Chemical Intermediates 46, p.4841–4851
DOI:	10.1007/s11164-020-04245-1
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

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