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    題名: Novel green and sustainable shape-stabilized phase change materials for thermal energy storage
    作者: Lai, Wei-Chi;Cai, Yi-Ting;Cai, Yan-Lin
    關鍵詞: Poly (ethylene glycol);Poly (L-lactic acid);Phase change material;Thermal energy storage
    日期: 2020-12-24
    上傳時間: 2021-03-17 12:11:06 (UTC+8)
    摘要: Poly (ethylene glycol) (PEG) blended with poly (L-lactic acid) (PLLA) as novel green and sustainable shape-stabilized phase change materials (PCMs) were prepared and characterized in this study. The miscibility and morphology of the blends played an important role in the properties of the PCMs. The partial miscibility between PEG and PLLA resulted in suitable latent heat and a low leakage percentage of PCMs. The typical spherulite structure with a Maltese cross was examined in neat PLLA, as observed using polarized optical microscopy. However, the addition of PEG to PLLA led to the formation of ring-banded spherulites due to the presence of PEG altering the aggregation and twisting the PLLA lamellae. These PLLA crystalline structures can capture liquid (including molten PEG), stabilize the shape, and prevent leakage. The thermal mechanical analysis results indicated that the thickness of the PEG/PLLA blends was not significantly changed during the phase change process. The PEG/PLLA 75/25 blends exhibited appropriate film forming properties and mechanical strength. Moreover, differential scanning calorimetry analysis demonstrated the largest latent heat of melting (130.26 J/g), which could have great potential for developing novel phase change materials for thermal energy storage.
    關聯: Journal of the Taiwan Institute of Chemical Engineers 117, p.257-264
    DOI: 10.1016/j.jtice.2020.12.013
    顯示於類別:[化學工程與材料工程學系暨研究所] 期刊論文


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