English  |  正體中文  |  简体中文  |  Items with full text/Total items : 56829/90592 (63%)
Visitors : 12149293      Online Users : 62
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/118980


    Title: Creation of 3D Textured Graphene/Si Schottky Junction Photocathode for Enhanced Photo-Electrochemical Efficiency and Stability
    Authors: Ku, Che-Kuei;Wu, Po-Hsien;Chung, Cheng-Chu;Chen, Chun-Chi;Tsai, Kai-Jie;Chen, Hung-Ming;Chang, Yu-Cheng;Chuang, Cheng-Hao;Wei, Chuan-Yu;Wen, Cheng-Yen;Lin, Tzu-Yao;Chen, Hsuen-Li;Wang, Yen-Shang;Lee, Zhe-Yu;Chang, Jun-Ru;Luo, Chih-Wei;Wang, Di-Yan;Hwang, Bing Joe;Chen, Chun-Wei
    Keywords: graphene;graphene/p‐Si Schottky junction;photo‐electrochemical cell;pyramid Si;water splitting
    Date: 2019-06-04
    Issue Date: 2020-07-27 12:10:17 (UTC+8)
    Publisher: Wiley-VCH Verlag GmbH & Co. KGaA
    Abstract: This work presents a novel photo‐electrochemical architecture based on the 3D pyramid‐like graphene/p‐Si Schottky junctions. Overcoming the conventional transfer technique by which only planar graphene/Si Schottky junctions are currently available, this work demonstrates the 3D pyramid‐like graphene/p‐Si Schottky junction photocathode, which greatly enhances light harvesting efficiency and exhibits promising photo‐electrochemical performance for hydrogen generation. The formation of 3D pyramid‐like graphene/p‐Si Schottky junctions exhibits enhanced electrochemical activity and promotes charge separation efficiency compared with the bare pyramid Si surface without graphene. The inherent chemical inertness of graphene significantly improves the operational stability of 3D graphene/p‐Si Schottky junction photo‐electrochemical cells. The 3D pyramid‐like graphene/p‐Si Schottky junction photocathode delivers an onset potential of 0.41 V and a saturated photocurrent density of −32.5 mA cm−2 at 0 V (vs RHE) with excellent stability comparable to values reported for textured or nanostructured p‐Si photocathodes coated with ultrathin oxide layers by the conventional atomic layer deposition technique. These results suggest that the formation of graphene/Si Schottky junctions with a 3D architecture is a promising approach to improve the performance and durability of Si‐based photo‐electrochemical systems for water splitting or solar‐to‐fuel conversion.
    Relation: Advanced Energy Materials 9(29), 1901022
    DOI: 10.1002/aenm.201901022
    Appears in Collections:[物理學系暨研究所] 期刊論文

    Files in This Item:

    File Description SizeFormat
    index.html0KbHTML2View/Open

    All items in 機構典藏 are protected by copyright, with all rights reserved.


    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback