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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/118698


    Title: Insights into dynamic molecular intercalation mechanism for Al-C battery by operando synchrotron x-ray techniques
    Authors: D. Y. Wang;S. K. Huang;H. J. Liao;Y. M. Chen;S. W. Wang;Y. T. Kao;J. Y. An;Y. C. Lee;C. H. Chuang;Y. C. Huang;Y. R. Lu;H. J. Lin;H. L. Chou;C. W. Chen;Y. H. Lai;C. L. Dong
    Keywords: Al ion battery;X-ray absorption spectroscopy;In-situ X-ray diffraction;Simulated core-level spectrum;Anion intercalation
    Date: 2019-05
    Issue Date: 2020-06-01 12:14:17 (UTC+8)
    Publisher: Elsevier Ltd
    Abstract: Recently, a novel rechargeable Al ion battery (AIB) with high performance has been developed. Owing to its low cost, high-rate capability, excellent cyclability, and non-flammability, AIB provides a safe alternative to many commercial batteries used in the energy storage system. To improve its performance, identifying molecular structure and arrangement of chloroaluminate anion (AlCl4−) intercalated in the graphite layer remains a great challenge. In this work, operando analysis of X-ray diffraction (XRD) measurement and X-ray absorption (XAS) spectroscopy were performed to investigate the intercalation of AlCl4− anion and related molecular arrangement in the graphite layers. The intercalated stage and intercalant gallery height of graphite cathode electrode during AIB battery operation were observed to be stage 3 and 9.22 Å, respectively. Furthermore, the spectral evolution from ex-situ XAS at the Al and Cl K-edge was associated with closely packed intercalation of AlCl4− molecules. With density functional theory (DFT) calculation, three simulated models of intercalated AlCl4− molecules in the graphite layer were revealed successfully, which explained possible molecular structures at different charging states. This analytical methodology paves the way for better understanding the structural transformation of molecular ions de-/intercalation in graphite layers.
    Relation: Carbon 146, p.528-534
    DOI: 10.1016/j.carbon.2019.01.038
    Appears in Collections:[電機工程學系暨研究所] 期刊論文

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