淡江大學機構典藏:Item 987654321/117742
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    题名: Comparisons of the electrochromic properties of Poly (hydroxymethyl 3, 4-ethylenedioxythiophene) and Poly (3, 4-ethylenedioxythiophene) thin films and the photoelectrochromic devices using these thin films
    作者: Lin, Cheng-Lan;Chen, Chih-Ying;Yu, Hsin-Fu;Ho, Kuo-Chuan
    关键词: Poly(hydroxymethyl 3,4-ethylenedioxythiophene);Poly(3,4- ethylenedioxythiophene);Electrochromic thin film;Photoelectrochromic device
    日期: 2019-11
    上传时间: 2019-10-31 12:10:18 (UTC+8)
    出版者: Elsevier
    摘要: Poly(hydroxymethyl 3,4-ethylenedioxythiophene) (PhmEDOT) and Poly(3,4- ethylenedioxythiophene) (PEDOT) thin films are prepared by electropolymerization method on indium tin oxide conducting glass in this study. Surface morphology of the thin films is observed using a scanning electron microscopy. Electrochemical and electrochromic properties including redox behaviors, UV–Vis absorbance spectra at different applying potentials, coloring/bleaching response times and transmittance modulation ability of the thin films are investigated. Photoelectrochromic devices (PECDs) composed of the PhmEDOT or the PEDOT thin films and dye-sensitized TiO2 photoanodes were assembled, and their photoelectrochromic performances compared. According to the obtained results, the PECD using the PhmEDOT thin film has faster photoelectrochromic coloring/bleaching rates and better transmittance modulation ability than the one using the PEDOT thin film.
    關聯: Sol. Energy Mater. Sol. Cells 202 (2019) 110132
    DOI: 10.1016/j.solmat.2019.110132
    显示于类别:[化學工程與材料工程學系暨研究所] 期刊論文

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