Experimental and DFT insights of the Zn-doping effects on the visible-light photocatalytic water splitting and dye decomposition over Zn-doped BiOBr photocatalysts

doi:10.1016/j.apcatb.2018.09.089

淡江大學機構典藏 > 理學院 > 物理學系暨研究所 > 期刊論文 > Item 987654321/117077

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题名:	Experimental and DFT insights of the Zn-doping effects on the visible-light photocatalytic water splitting and dye decomposition over Zn-doped BiOBr photocatalysts
作者:	Junqiu Guo;Xin Liao;Ming-Hsien Lee;Geoff Hyett;Chung-Che Huang;Daniel W. Hewak;Sakellaris Mailis;Wei Zhou;Zheng Jiang
关键词:	Photocatalysis;Zn-doped BiOBr;Photoelectrochemistry;Band structure;DFT
日期:	2019-04-15
上传时间:	2019-09-21 12:10:38 (UTC+8)
出版者:	Elsevier
摘要:	Synergetic experimental and DFT insights of energy band structures and photogenerated rate-limiting reactive species are indispensable to design impurity-doped photocatalysts for photocatalytic environment remediation and solar fuels. Herein, despite the larger bandgap (Eg) of the Zn-doped BiOBr samples, they exhibited superior activity to BiOBr in the photocatalytic water splitting but impaired the photodegradation of Rhodamine B under visible-light illumination. Based on the spectral and electrochemical impedance characterisations and DFT simulations, the wider bandgaps of Zn-doped BiOBr samples were explicitly assigned to the more positive valence band maxima (VBM) and more negative conduction band minima (CBM). The enhanced photocatalytic water splitting on the Zn-doped BiOBr was arisen from the higher redox chemical potentials of charge carriers on respective CBM and VBM, suppressed back reactions and depressed recombination of photogenerated charge carriers. However, the reduced e−-h+ recombination on the Zn-doped BiOBr cannot cancel the detrimental influences from the weaker light absorption and dye-sensitisation effects, leading to slower RhB photodegradation.
關聯:	Applied Catalysis B: Environmental 243, p.502-512
DOI:	10.1016/j.apcatb.2018.09.089
显示于类别:	[物理學系暨研究所] 期刊論文

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