The activity of electrocatalysts strongly depends on the number of active sites, which can be increased by downsizing electrocatalysts. Single‐atom catalysts have attracted special attention due to atomic‐scale active sites. However, it is a huge challenge to obtain atomic‐scale CoOx catalysts. The Co‐based metal–organic frameworks (MOFs) own atomically dispersed Co ions, which motivates to design a possible pathway to partially on‐site transform these Co ions to active atomic‐scale CoOx species, while reserving the highly porous features of MOFs. In this work, for the first time, the targeted on‐site formation of atomic‐scale CoOx species is realized in ZIF‐67 by O2 plasma. The abundant pores in ZIF‐67 provide channels for O2 plasma to activate the Co ions in MOFs to on‐site produce atomic‐scale CoOx species, which act as the active sites to catalyze the oxygen evolution reaction with an even better activity than RuO2.
