本研究將含有高壓容器容積比例為80%之二乙烯苯單體、乙酸乙酯溶劑及偶氮二異丁腈起始劑之A混合溶液，進行高壓溶劑熱法已成功製備具有超斥水之聚二乙烯苯(PDVB)合成物，壓製成PDVB超斥水薄片，其靜態接觸角與滑動角分別約為163°及1°，將含有2wt% PDVB超斥水粉末之乙醇溶液給予球磨後，製得平均粒徑約為148nm PDVB的乙醇懸浮溶液。使用浸塗法製得靜態接觸角分別約為153°、154°及157°與滑動角均約為1°的超斥水影印紙、道林紙與西卡紙。將已去木質素的木塊與含有高壓容器容積比例為80%之A混合溶液，經高壓溶劑熱法已成功製備具有超斥水之靜態接觸角分別約為135°、132°及140°與滑動角均約為1°的超斥水白楊木、吉野檜木及飛機木塊。將已作陽極處理且未封孔之6061鋁合金與含有高壓容器容積比例為80%之A混合溶液，使用5次的高壓溶劑熱法，讓PDVB超斥水合成物填滿陽極處理之AAO孔洞中，成功製得靜態接觸角約為156°的超斥水陽極處理之6061鋁合金。 In this research, we have been successively prepared a non-toxic and superhydrophobic polydivinylbenzene(PDVB) particulates by high pressure solvothermal method with mixture A, which including divinylbenzene monomer, ethyl acetate solvent and azobisisobutyronitrile initiator with 80% high pressure vessel volume. PDVB sheet’s contact angle (CA) and sliding angle (SA) are approximately 163° and 1°. Using ball milling process to produce 2wt% PDVB in ethanol suspension solution with the average particle size of PDVB is about 148nm. Superhydrophobic paper was obtained by dip-coating with the PDVB suspension solution onto copy & laser paper, wood free paper and Bristol board presenting CA/SA approximately 153°/1°, 154°/1° and 157°/1°. Superhydrophobic wood was obtained by high pressure solvothermal method using wood without lignin and mixture A with 80% high pressure vessel volume. Superhydrophobic wood was presented by Poplar, Chamaecyparis formosensis and Baltimore which had 135°/1°, 132°/1° and 140°/1° of CA/SA. Superhydrophobic anodized but without sealing aluminum alloy sheet was prepared by repeating 5 times high pressure solvothermal method several times with 80% high pressure vessel volume of mixture A in order to let PDVB filled up AAO pores thus enhance durability. Superhydrophobic aluminum alloy presented 156° of CA.
