English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 60696/93562 (65%)
造訪人次 : 1041848      線上人數 : 26
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/113672


    題名: Visible light-induced electronic structure modulation of Nb- and Ta-doped α-Fe2O3 nanorods for effective photoelectrochemical water splitting
    作者: Han-Wei Chang;Yanming Fu;Wan-Yi Lee;Ying-Rui Lu;Yu-Cheng Huang;Jeng-Lung Chen;Chi-Liang Chen;Wu Ching Chou;Jin-Ming Chen;Jyh-Fu Lee
    日期: 2018-01-08
    上傳時間: 2018-06-09 12:10:16 (UTC+8)
    摘要: The photoelectrochemical (PEC) water splitting activity of Nb and Ta-doped hematite (α-Fe2O3) nanorods was investigated with reference to electronic structures by in situ synchrotron x-ray absorption spectroscopy (XAS). Current density-potential measurements demonstrate that the PEC activity of α-Fe2O3 nanorods depends strongly on the species and concentrations of dopants. The doping of α-Fe2O3 nanorods with a low level of Nb or Ta can improve their electrical conductivity and thereby facilitate charge transport and reduced electron–hole recombination therein. The photoconversion effects of Nb and Ta-doped α-Fe2O3 by in situ XAS in the dark and under illumination revealed opposite evolutions of the spectral intensities of the Fe L-edge and Nb/Ta L-edge, indicating that charge transfer and a conduction pathway are involved in the photoconversion. Analytic in situ XAS results reveal that the α-Fe2O3 that is doped with a low level of Nb has a greater photoconversion efficiency than that doped with Ta because Nb sites are more active than Ta sites in α-Fe2O3. The correlation between PEC activity and the electronic structure of Nb/Ta-doped α-Fe2O3 is examined in detail using in situ XAS and helps to elucidate the mechanism of PEC water splitting in terms of the electronic structure.
    關聯: Nanotechnology 29(6),064002(8 pages)
    DOI: 10.1088/1361-6528/aa9d75
    顯示於類別:[物理學系暨研究所] 期刊論文

    文件中的檔案:

    檔案 描述 大小格式瀏覽次數
    index.html0KbHTML143檢視/開啟
    Visible light-induced electronic structure modulation of Nb- and Ta-doped Fe2O3 nanorods for efficient solar water splitting.pdf2360KbAdobe PDF1檢視/開啟

    在機構典藏中所有的資料項目都受到原著作權保護.

    TAIR相關文章

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋