Polynuclear Silver(I) Triazole Complexes: Ion Conduction and Nanowire Formation in the Mesophase

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/109849

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題名:	Polynuclear Silver(I) Triazole Complexes: Ion Conduction and Nanowire Formation in the Mesophase
作者:	Su, Padi Y. S.;Hsu, S. J.;Tseng, Jing C. W.;Hsu, Hsiu-Fu;Wang, Wen-Jwu;Lin, Ivan J. B.
日期:	2016-01-04
上傳時間:	2017-03-10 02:17:35 (UTC+8)
出版者:	Wiley
摘要:	Examples of polynuclear metallomesogens are few. Herein,1,2,4-triazole ligands were used to prepare mono- and polynuclear silver(I) triazole metallomesogens. Besides showing an SmA phase in the mesophase, two interesting properties were observed. First, higher ion conductivity is always found for the polynuclear complexes than for the mononuclear complexes with the same anion, an observation contrary to the knowledge that migration of a monomeric cation should be faster than that of a polymeric cation. Second, thermolysis of the polynuclear silver(I) triazole complexes in the assembled mesophase yielded Ag nanowires, in an excellent demonstration of the assembled nature of the polynuclear silver(I) ions in the thermolysis process.
關聯:	Chemistry 22(1), pp.323-330
DOI:	10.1002/chem.201502823
顯示於類別:	[化學學系暨研究所] 期刊論文

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