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    题名: Polynuclear Silver(I) Triazole Complexes: Ion Conduction and Nanowire Formation in the Mesophase
    作者: Su, Padi Y. S.;Hsu, S. J.;Tseng, Jing C. W.;Hsu, Hsiu-Fu;Wang, Wen-Jwu;Lin, Ivan J. B.
    日期: 2016-01-04
    上传时间: 2017-03-10 02:17:35 (UTC+8)
    出版者: Wiley
    摘要: Examples of polynuclear metallomesogens are few. Herein,1,2,4-triazole ligands were used to prepare mono- and polynuclear silver(I) triazole metallomesogens. Besides showing an SmA phase in the mesophase, two interesting properties were observed. First, higher ion conductivity is always found for the polynuclear complexes than for the mononuclear complexes with the same anion, an observation contrary to the knowledge that migration of a monomeric cation should be faster than that of a polymeric cation. Second, thermolysis of the polynuclear silver(I) triazole complexes in the assembled mesophase yielded Ag nanowires, in an excellent demonstration of the assembled nature of the polynuclear silver(I) ions in the thermolysis process.
    關聯: Chemistry 22(1), pp.323-330
    DOI: 10.1002/chem.201502823
    显示于类别:[化學學系暨研究所] 期刊論文


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