淡江大學機構典藏:Item 987654321/107885
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    題名: Pressure-induced electron transfer in quasi-molecular solids
    作者: Hsueh, H. C.;Poon, W. C. K.;Vass, H.;Crain, J.
    日期: 1996-09-20
    上傳時間: 2016-10-13 02:10:20 (UTC+8)
    摘要: A combination of Raman scattering and synchrotron X-ray powder diffraction on Group-V metal triiodides (XI3, X = As,Sb,Bi) has revealed a continuous isostructural transition from a molecular solid to a two-dimensional layered crystal under high pressure. The loss of molecular identity proceeds by gradual pressure-induced electron transfer from intramolecular to intermolecular bonds and suppression of sp3 hybridisation. Initial pressure increase has the effect of destroying molecular units while continued compression enhances intralayer cohesion. These two effects give rise to a non-monotonic pressure variation of the X-I bond-stretching frequency.
    關聯: Europhysics Letters 35(9), pp.689-694
    DOI: 10.1209/epl/i1996-00171-0
    顯示於類別:[物理學系暨研究所] 期刊論文

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