淡江大學機構典藏:Item 987654321/107092
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    题名: Electronic structure and field emission properties of nitrogen doped graphene nano-flakes (GNFs:N) and carbon nanotubes (CNTs: N)
    作者: Ray, S.C.;Pong, W.F.;Papakonstantinou P.
    关键词: X-ray absorption near edge structure (XANES) spectroscopy
    日期: 2015-12-17
    上传时间: 2016-08-15
    出版者: Elsevier BV * North-Holland
    摘要: Substitution of hetero-atom doping is a promising route to modulate the outstanding material properties of carbon nanotubes and graphene for customized applications. Nitrogen-doping has been introduced to ensure tunable work-function, enhanced n-type carrier concentration, diminished surface energy, and manageable polarization. Along with the promising assessment of N-doping effects, research on the N-doped carbon based composite structures is emerging for the synergistic integration with various functional materials. Nitrogen undoped/doped graphene nano-flakes (GNFs/GNFs:N) and multiwall carbon nano-tubes (MWCNTs/MWCNTs:N) are used for comparative study of their electronic/bonding structure along with their defects state. X-ray absorption near edge structure (XANES) spectroscopy shows that the GNFs:N produce mainly pyridine like structure; whereas MWCNTs:N shows graphitic nitrogen atoms are attached with the carbon lattice. The ID/IG ratio obtained from Raman spectroscopy shows that the defects is higher in MWCNTs:N than GNFs:N. The electron field emission result shows that the turn on electric field is lower (higher electron emission current) in case of MWCNTs:N than GNFs:N and are good agreement with XANES and the results obtained from Raman spectra.
    關聯: Applied Surface Science 380, pp.301-304
    DOI: 10.1016/j.apsusc.2015.12.098
    显示于类别:[物理學系暨研究所] 期刊論文

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