Reinvestigation of ortho-amidoacetophenones' cyclization mediated by trimethylsilyl trifluoromethanesulfonate. The Lewis-acid-assisted and Brønsted-acid-catalyzed reaction

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/106197

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题名:	Reinvestigation of ortho-amidoacetophenones' cyclization mediated by trimethylsilyl trifluoromethanesulfonate. The Lewis-acid-assisted and Brønsted-acid-catalyzed reaction
作者:	Chen, Yi-Ru;Cho, Yu Cheng;Shih, Tzenge-Lien
关键词:	Methylquinoline;Quinolone;Trifluoromethanesulfonic acid;Trimethylsilyl trifluoromethanesulfonate;Lewis-acid-assisted and Brønsted-acid-catalyzed reaction
日期:	2016-04-21
上传时间:	2016-04-22 13:24:04 (UTC+8)
出版者:	Pergamon Press
摘要:	Reinvestigation the synthesis of quinolones from ortho-amidoacetophenones by trimethylsilyl trifluoromethanesulfonate (TMSOTf) mediated reaction is reported. In addition to receiving the expected quinolones, an unexpected intermolecular self-condensation adduct was also isolated. The detailed mechanism of its formation is discussed.
關聯:	Tetrahedron 72(16), pp.2006-2011
DOI:	10.1016/j.tet.2016.02.068
显示于类别:	[化學學系暨研究所] 期刊論文

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