這樣的結果是形成一個離子化合物，反應上有別於HDPA橋基氮上取代的簡易的反應程序以及最後的高產率。這樣的衍生物雖然與金屬上配位是不太可行的，但由於烷鏈末端是高反應性的碘，而有高反應性，在於衍生上還是有很大的可能。 In this research, new ionic compounds base on 1,10-phenanthroline, L1 and L2 were synthesized with high yield. L1 was synthesised by the reaction of macrocyclic molecule HDPA (bis(1,10-phenanthrolin-2-yl)amine) with 1,6-diiodohexane. The L1 was designed for different reaction site with HDPA derivatives synthesized in other research. L1 is synthesized by the modification of phenanthroline instead of bridge nitrogen of HDPA and generate an asymmetric structure. L2 was synthesized by the exchange of anion for the solubility. The H-H COSY, HMQC and HMBC technology were used for solving the aromatic signal of L1 and L2. And L1 and L2 were identified by ESI-MS. The acid titration UV-Vis experiments shows Pka of L1 was 3.13 and Pka of L2 was 2.98. The oxidation potential of L1 were -0.19 eV, -0.89 eV and L2 were -0.73 eV, -1.07 eV. The reduction otenrial of L1 were 0.68 eV, 0.93 eV and L2 were 0.76 eV, 0.88 eV.
