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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/104674


    Title: An Unconventional Approach to Induce Liquid-Crystalline Phases of Triazine-Based Dendrons by Breaking Their Self-Assembly into Dimers
    Authors: Long-Li Lai;Jei-Way Hsien;Yung-Hao Chang;Ming-Yu Kuo;Kung-Lung Cheng;Shih-Hsien Liu;Hsiu-Fu Hsu
    Date: 2015-09-14
    Issue Date: 2016-01-06 11:06:49 (UTC+8)
    Abstract: Three triazine-based dendrons (1 a-c) were successfully prepared in 70-83 % yields. These newly prepared dendrons are found to be liquid crystalline (LC). Computational investigations on molecular conformations and dipoles of triazine-based dendrons reveal that the substituent on the central triazine unit interrupts strong dipole or H-bond interactions to avoid dimeric formation. The obtained dendrons, not favouring self-assembly into dimers but showing LC behaviours, provides evidence for an approach contrary to the conventional method of inducing LC behaviours of dendrons by dimer or trimer formation, mostly through H-bond interactions.
    Relation: Chemistry 21(38), pp.13336-13343
    DOI: 10.1002/chem.201501743
    Appears in Collections:[化學學系暨研究所] 期刊論文

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