Evidence of"new hot spots"from determining the nonlinear optical behavior of materials:mechanistic studies of the vanadium borate crystal,Na3VO2B6O11

機構典藏 > College of Sciences > Graduate Institute & Department of Physics > Journal Article > Item 987654321/104608

Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/104608

Title:	Evidence of"new hot spots"from determining the nonlinear optical behavior of materials:mechanistic studies of the vanadium borate crystal,Na3VO2B6O11
Authors:	Xin Su;Zhihua Yang;Ming-Hsien Lee;Shilie Pan;Ying Wang;Xiaoyun Fan;Zhenjun Huang;Bingbing Zhang
Date:	2015-02-21
Issue Date:	2016-01-06 11:04:40 (UTC+8)
Abstract:	A novel mechanism for the nonlinear optical (NLO) effects of vanadium borate crystals, Na3VO2B6O11 (NVB), with distorted VO4 groups was investigated. A comprehensive analysis of the structure-property relationship was performed by combining the experimental measurements, the electronic structures calculations, the SHG-weighted electron density and the real-space atom-contribution analysis to yield the linear and nonlinear optical properties. The contribution of a (VO4)(3-) anionic group to the second harmonic generation (SHG) response was more pronounced than that of the (BO3)(3-) anionic group, which plays a virtual role in the SHG effects in NVB. The anionic (BO3)(3-) groups make dominant contributions to the birefringence, whereas the contribution of the V(5+) cations to these linear optical effects is negligible
Relation:	Physical Chemistry Chemical Physics 17(7), pp.5338-5344
DOI:	10.1039/c4cp04248d
Appears in Collections:	[Graduate Institute & Department of Physics] Journal Article

Files in This Item:

File	Description	Size	Format
Evidence of new hot spots from determining the nonlinear optical behavior of materials mechanistic studies of the vanadium borate crystal Na3VO2B6O11.pdf		2116Kb	Adobe PDF	2	View/Open
index.html		0Kb	HTML	158	View/Open