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    题名: Hydride-Induced Anionic Cyclization: An Efficient Method for the Synthesis of 6-H-Phenanthridines via a Transition-Metal-Free Process
    作者: 謝仁傑
    日期: 2015
    上传时间: 2015-07-28 16:28:17 (UTC+8)
    出版者: ACS
    摘要: A novel procedure for hydride-induced anionic cyclization has been developed. It includes the reduction of a biaryl bromo-nitrile with a nucleophilic aromatic substitution (SNAr). A range of polysubstituted 6-H-phenanthridines were so obtained in moderate to good yield with good substrate tolerance. This method involves a concise transition-metal-free process and was applied to synthesize natural alkaloids.
    關聯: Organic Letters, 2015, 17(6), pp. 1613–1616.
    DOI: 10.1021/acs.orglett.5b00544
    显示于类别:[化學學系暨研究所] 期刊論文

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