層狀材料TiSe2之電荷密度波研究

淡江大學機構典藏 > 理學院 > 物理學系暨研究所 > 學位論文 > Item 987654321/101583

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題名:	層狀材料TiSe2之電荷密度波研究
其他題名:	Study of charge-density waves in the layered material TiSe2
作者:	鄭智謙;Cheng, Chih-Chien
貢獻者:	淡江大學物理學系碩士班杜昭宏
關鍵詞:	硬X光;電荷密度波;層狀材料;Hard X-ray;Charge-Density Wave;Layered Material
日期:	2014
上傳時間:	2015-05-01 16:10:59 (UTC+8)
摘要:	電荷密度波(CDW)常出現於低維度材料，即具有異向性一維的線性鏈或二維的平面的材料，如K0.3MoO3、NbSe3、TaS2、 K2Pt(CN)4Br0.332H2O等皆屬於這類的材料；在眾多電荷密度波材料中，二維層狀結構的TiSe2已受到長時間的關注，據文獻記載其電荷密度波會出現於(H±0.5 K±0.5 L±0.5)的位置並為對掌形電荷有序。在經過退火過後， TiSe2受溫度影響Se元素會有些許消散使晶格排列改變，如此一來可能會造成相變溫度的轉變，本論文利用電子微探分析(Electron Probe Microanalyzer)確定Se含量，並藉由電性和磁性量測來估計其相變溫度，並藉由X-ray的散射來確認實際TiSe2的電荷密度波相變溫度，如此能了解不同的退火溫度樣品的品質會出現差異，且探討Se含量和退火溫度對相變溫度造成的影響。 The modulated structure due to the formation of charge density wave (CDW) usually exists in low-dimensional materals, such as K0.3MoO3, NbSe3, TaS2, K2Pt(CN)4Br0.332H2O　and so on. The study of the charge modulations are mostly relied on the use of electron beams, x-rays, and neutrons. Among them, x-rays have the merits of high-spatial resolution and sensitive to charges over other two probes. In this study, we use the high-resolution x-rays to investigate the CDW modulation in a layered compound TiSe2 under different annealing temperatures. Measurements on a series of crystals of TiSe2 being annealed at different temperatures show the different conductivity behavior, which were observed to relate to the Se contents by the use of Electron Probe X-Ray Microanalyzer.Using high-resolution x-ray scattering, many satellite reflections caused by the CDW were located at positions (H± 0.5 K± 0.5 L± 0.5) at low temperatures, and the transition temperature of CDW was also observed to depend on annealing temperatures.
顯示於類別:	[物理學系暨研究所] 學位論文

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